The application of quantum theory to atomic and molecular structure, and the interaction between electromagnetic radiation and atoms and simple molecules.
1:00 to 2:20 pm
Wednesday, October 23, 2019
7:00p - 9:00p
Friday, December 6, 2019
11:30a - 1:30p
Instructor: Michael Massa
Telephone: +1-519-824-4120 x52625
Office: MACN 328
Office Hours: TBA, and will be arranged at the first lecture
Two assessment schemes will be considered. The scheme which yields the higher score will automatically be applied.
Part 1: Atoms (~70%)
- Overview of atomic structure: Interaction and energy scales, qualitative effect of spin, Pauli principle. Some spectroscopic notation.
- Central forces and Angular momentum: Conmmutator relations, ladder operators, review of hydrogen atom solutions, spherical harmonics, spin angular momentum, addition of angular momentum.
- Dealing with many electrons: Pauli principle, anti-symmetrization. Variational principle with application to He, H-. Approximate treatment of more than two electrons – independent particle picture + perturbation treatment of e-e repulsion.
- Fine structure (spin-orbit coupling), hyperfine structure (nuclear spin and shape effects).
- External perturbations: Zeeman and Stark effects.
- Transition probabilities: Selection rules, Fermi’s golden rule.
Part 2: Molecules (~30%)
- Born-Oppenheimer separation: Variational treatment of H2+. Molecular orbitals and qualitative treatment of H2 and first-row two diatomic molecules. Van der Waals forces.
- Vibration and rotation of diatomic molecules. Separation of variables, harmonic vibration and simple rotation. Anharmonic effects. Morse potential. Interpretation of molecular spectra, deduction of molecular constants. Selection rules, (nuclear) spin statistics. Thermal effects.
- Courselink (Website)
The course website can be found by logging into Courselink.uoguelph.ca
- The Fundamentals of Atomic and Molecular Physics (Textbook)
R.L. Brooks, Springer 2013.
- References (Readings)
Familiarity with a quantum text of your choice is essential. Griffiths’ “Quantum Mechanics” covers some of the material in this course. Gerhard Herzberg’s “Atomic spectra and atomic structure” and “Molecular spectra and molecular structure, Vol 1” are gold mines of experimental information with wonderful qualitative discussions.
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When you find yourself unable to meet an in-course requirement because of illness or compassionate reasons please advise the course instructor (or designated person, such as a teaching assistant) in writing, with your name, id#, and e-mail contact. The grounds for Academic Consideration are detailed in the Undergraduate and Graduate Calendars.
Undergraduate Calendar - Academic Consideration and Appeals
Graduate Calendar - Grounds for Academic Consideration
Associate Diploma Calendar - Academic Consideration, Appeals and Petitions
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Undergraduate Calendar - Dropping Courses
Graduate Calendar - Registration Changes
Associate Diploma Calendar - Dropping Courses
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Keep paper and/or other reliable back-up copies of all out-of-class assignments: you may be asked to resubmit work at any time.
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When accommodations are needed, the student is required to first register with Student Accessibility Services (SAS). Documentation to substantiate the existence of a disability is required; however, interim accommodations may be possible while that process is underway.
Accommodations are available for both permanent and temporary disabilities. It should be noted that common illnesses such as a cold or the flu do not constitute a disability.
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For Guelph students, information can be found on the SAS website
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Please note: Whether or not a student intended to commit academic misconduct is not relevant for a finding of guilt. Hurried or careless submission of assignments does not excuse students from responsibility for verifying the academic integrity of their work before submitting it. Students who are in any doubt as to whether an action on their part could be construed as an academic offence should consult with a faculty member or faculty advisor.
Undergraduate Calendar - Academic Misconduct
Graduate Calendar - Academic Misconduct
Recording of Materials
Presentations that are made in relation to course work - including lectures - cannot be recorded or copied without the permission of the presenter, whether the instructor, a student, or guest lecturer. Material recorded with permission is restricted to use for that course unless further permission is granted.
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Please note: This is a preliminary web course description. The department reserves the right to change without notice any information in this description. An official course outline will be distributed in the first class of the semester and/or posted on Courselink.